Reduction of carbon dioxide and organic carbonyls by hydrosilanes catalysed by the perrhenate anion
Author:
Affiliation:
1. EaStCHEM School of Chemistry
2. University of Edinburgh
3. Edinburgh EH9 3FJ
4. UK
5. Catalysis Research Center
6. Technische Universität München
7. D-85747 Garching bei München
8. Germany
Abstract
A simple quaternary ammonium perrhenate salt catalyses the hydrosilylation of aldehydes, ketones, and carbon dioxide, and the methylation of amines using carbon dioxide. DFT calculations show that a perrhenate hypervalent silicate interacts directly with CO2.
Funder
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CY/C7CY00772H
Reference89 articles.
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4. Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes
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