Copper-catalyzed C–C bond-forming transformation of CO2 to alcohol oxidation level: selective synthesis of homoallylic alcohols from allenes, CO2, and hydrosilanes-Reference-Cited by-同舟云学术

Copper-catalyzed C–C bond-forming transformation of CO2 to alcohol oxidation level: selective synthesis of homoallylic alcohols from allenes, CO2, and hydrosilanes

Published:2015 Issue:65 Volume:51 Page:13020-13023
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Tani Yosuke¹²³⁴⁵,Kuga Kazunari¹²³⁴⁵,Fujihara Tetsuaki¹²³⁴⁵,Terao Jun¹²³⁴⁵,Tsuji Yasushi¹²³⁴⁵

Affiliation:

1. Department of Energy and Hydrocarbon Chemistry

2. Graduate School of Engineering

3. Kyoto University

4. Kyoto 615-8510

5. Japan

Abstract

Title transformation has been disclosed wherein CO₂ is chemoselectively reduced to the alcohol oxidation level to provide homoallylic alcohols, with esters or other reducible functionalities on the allenes being intact.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC03932K

Reference55 articles.

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3. Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2

4. Transformation of Carbon Dioxide

5. A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2

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