High intrinsic thermally conductivity side-chain liquid crystalline polysiloxane films grafted with pendent difunctional mesogenic groups

Author:

Zheng Xiaole123,Zhan Yingjie134,Liu Yingchun134,Lu Maoping123,Jiao Enxiang135,Zhang Hangzhen136,Shi Jun156ORCID,Lu Mangeng145ORCID,Wu Kun13ORCID

Affiliation:

1. Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, People's Republic of China

2. Guangdong Provincial Key Laboratory of Organic Polymer Materials for Electronics, Guangzhou 510650, People's Republic of China

3. University of Chinese Academy of Sciences, Beijing 100049, People's Republic of China

4. CAS Engineering Laboratory for Special Fine Chemicals, Guangzhou 510650, People's Republic of China

5. New Materials Research Institute of CASCHEM (Chongqing) Co., Ltd, Chongqing, 400714, PR China

6. CASH GCC Shaoguan Research Institute of Advanced Materials Co., Ltd, Shaoguan 512400, People's Republic of China

Abstract

Herein, the microscopic ordered aggregation morphologies of SCLCP films are investigated, and molecular structures with regular arrangement can increase heat transfer via suppressing the scattering of phonons, thus greatly improving the λ of SCLCPs.

Funder

Key Project of Application Development Plan of Chongqing City

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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