Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion-Reference-Cited by-同舟云学术

Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion

Published:2018 Issue:25 Volume:9 Page:5600-5607
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Omann Lukas¹²³⁴^ORCID,Pudasaini Bimal⁵⁶⁷⁸^ORCID,Irran Elisabeth¹²³⁴^ORCID,Klare Hendrik F. T.¹²³⁴^ORCID,Baik Mu-Hyun⁵⁶⁷⁸⁹^ORCID,Oestreich Martin¹²³⁴^ORCID

Affiliation:

1. Institut für Chemie

2. Technische Universität Berlin

3. 10623 Berlin

4. Germany

5. Center for Catalytic Hydrocarbon Functionalizations

6. Institute for Basic Science (IBS)

7. Daejeon

8. Republic of Korea

9. Department of Chemistry

Abstract

Substituent exchange reactions of silylium ions can be steered in opposite directions. The judicious choice of the hydrosilane and the counteranion enables the selective formation of either triaryl- or trialkylsilylium ions.

Funder

Einstein Stiftung Berlin

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01833B

Reference47 articles.

1. V. Y. Lee and A.Sekiguchi , in Organosilicon Compounds , ed. V. Y. Lee , Academic Press , Oxford , 2017 , vol. 1 , pp. 197–230

2. T. Müller , in Structure and Bonding , ed. D. Scheschkewitz , Springer , Berlin , 2014 , vol. 155 , pp. 107–162

3. T. Müller , in Science of Synthesis Knowledge Updates 2013/3 , ed. M. Oestreich , Thieme , Stuttgart , 2013 , pp. 1–42