Highly selective synthesis of substituted (E)-alkenylsilatranes via catalytic trans-silylation and mechanistic implications-Reference-Cited by-同舟云学术

Highly selective synthesis of substituted (E)-alkenylsilatranes via catalytic trans-silylation and mechanistic implications

Published:2017 Issue:15 Volume:46 Page:4975-4981
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sztorch Bogna¹²³⁴,Frąckowiak Dawid¹⁵³⁴,Pyziak Jadwiga¹⁵³⁴,Czapik Agnieszka¹⁵³⁴,Hoffmann Marcin¹²³⁴,Marciniec Bogdan¹²³⁴¹^ORCID

Affiliation:

1. Adam Mickiewicz University in Poznań

2. Faculty of Chemistry

3. 61-614 Poznań

4. Poland

5. Centre for Advanced Technologies

Abstract

A new catalytic protocol for the synthesis of functionalized alkenylsilatranes has been developed based on ruthenium catalyzed trans-silylation with olefins. A ruthenium silatranyl complex has been prepared and characterized.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00201G

Reference33 articles.

1. Metallatranes

2. Main group atranes: chemical and structural features

3. Silatranes: a review on their synthesis, structure, reactivity and applications

4. Histochemical study of the pilotropic action of 1-(chloromethyl)-silatrane on guinea pig skin

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