Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations-Reference-Cited by-同舟云学术

Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations

Published:2020-03-10 Issue:1 Volume:26 Page:33-36
ISSN:2191-0197
Container-title:Heterocyclic Communications
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Author:

Sztorch Bogna¹,Frąckowiak Dawid²,Marciniec Bogdan³²

Affiliation:

1. Adam Mickiewicz University in Poznań, Center for Advanced Technology, Uniwersytetu Poznańskiego 10, 61-614Poznań, Poland

2. Center for Advanced Technology, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 10, 61-614Poznań, Poland

3. Adam Mickiewicz University in Poznań, Faculty of Chemistry, Uniwersytetu Poznańskiego 8, 61-614Poznań, Poland

Abstract

AbstractWe have developed a new effective route for obtaining (E)-vinyl-substituted silatranes via ruthenium-catalyzed silylative coupling of 1-allylsilatrane with olefins. Experimental research allowed us also to propose the mechanism of the process based on stoichiometric reactions.

Publisher

Walter de Gruyter GmbH

Subject

Organic Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/hc-2020-0006/pdf

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