Affiliation:
1. Department of Chemistry & Biology Toronto Metropolitan University 350 Victoria St. Toronto ON, M5B 2K3 Canada
2. Department of Chemistry McGill University 801 Sherbrooke St. W. Montreal QC, H3A 0B8 Canada
Abstract
AbstractHomoallylic amines prepared via addition of allylsilanes often require preformed imine substrates, metal catalysts, fluoride activators, or use of protected amines. In this metal‐free, air‐ and water‐tolerant procedure, aromatic aldehyde and aniline substrates undergo direct alkylative amination using easily accessible 1‐allylsilatrane.
Funder
Natural Sciences and Engineering Research Council of Canada
Subject
General Chemistry,Catalysis,Organic Chemistry