A new anthraquinoid ligand for the iron-catalyzed hydrosilylation of carbonyl compounds at room temperature: new insights and kinetics

Author:

Raya-Barón Álvaro12345,Galdeano-Ruano Carmen P.12345,Oña-Burgos Pascual12345,Rodríguez-Diéguez Antonio67895ORCID,Langer Robert610111213ORCID,López-Ruiz Rosalía12345ORCID,Romero-González Roberto12345,Kuzu Istemi610111213ORCID,Fernández Ignacio12345ORCID

Affiliation:

1. Department of Chemistry and Physics

2. Research Centre CIAIMBITAL

3. Universidad de Almería

4. 04120 Almería

5. Spain

6. Department of Inorganic Chemistry

7. Faculty of Science

8. University of Granada

9. 18070 Granada

10. Fachbereich Chemie

11. Philipps-Universität Marburg

12. 35032 Marburg

13. Germany

Abstract

The synthesis and characterization of a highly active Fe(ii) catalyst for the hydrosilylation of aldehydes and ketones have been described.

Funder

Agencia de Innovación y Desarrollo de Andalucía

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference79 articles.

1. V. B. Pukhnarevich , E.Lukevics , L. I.Kopylova and M. G.Voronkov , Perspectives of Hydrosilylation , Institute of Organic Synthesis , Riga, Latvia , 1992

2. I. Ojima , Z.Li and J.Zhu , in The Chemistry of Organic Silicon Compounds , ed. Z. Rappoport and Y. Apeloig , John Wiley & Sons , New York , 1998 , Vol. 2

3. H. Nishiyama and K.Itoh , in Catalytic Asymmetric Synthesis , ed. I. Ojima , Wiley-VCH , New York , 2000

4. Hydrosilylation of carbon dioxide catalysed by ruthenium complexes

5. From Carbon Dioxide to Methane:  Homogeneous Reduction of Carbon Dioxide with Hydrosilanes Catalyzed by Zirconium−Borane Complexes

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