Cyclic polylactide synthesis initiated by a lithium anthraquinoid: understanding the selectivity through DFT and diffusion NMR-Reference-Cited by-同舟云学术

Cyclic polylactide synthesis initiated by a lithium anthraquinoid: understanding the selectivity through DFT and diffusion NMR

Published:2021 Issue:28 Volume:12 Page:4083-4092
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Martínez Cristina Ruiz¹²³⁴⁵^ORCID,Pérez Juana M.¹²³⁴⁵^ORCID,Arrabal-Campos Francisco M.¹²³⁴⁵,Batuecas María¹²³⁴⁵,Ortuño Manuel A.⁶⁷⁸⁵⁹^ORCID,Fernández Ignacio¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Physics

2. Research Centre CIAIMBITAL

3. University of Almería

4. 04120

5. Spain

6. Institute of Chemical Research of Catalonia (ICIQ)

7. The Barcelona Institute of Science and Technology (BIST)

8. 43007 Tarragona

9. Centro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS)

Abstract

We present herein the application of a lithium anthraquinoid in the catalytic synthesis of cyclic PLA, showing that the aggregation plays a critical role in cyclic vs. linear selectivity.

Funder

Ministerio de Ciencia e Innovación

Agència de Gestió d'Ajuts Universitaris i de Recerca

Xunta de Galicia

Centro Singular de Investigación de Galicia

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D1PY00547B

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