Facile and efficient synthesis of 1-haloalkynes via DBU-mediated reaction of terminal alkynes and N-haloimides under mild conditions-Reference-Cited by-同舟云学术

Facile and efficient synthesis of 1-haloalkynes via DBU-mediated reaction of terminal alkynes and N-haloimides under mild conditions

Published:2014 Issue:57 Volume:4 Page:30046-30049
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Li Mengru¹²³,Li Yueju¹²³,Zhao Baozhong¹²³,Liang Fushun¹²³,Jin Long-Yi⁴⁵⁶

Affiliation:

1. Department of Chemistry

2. Northeast Normal University

3. Changchun 130024, China

4. Faculty of Chemistry

5. Yanbian University

6. Yanji 133002, China

Abstract

Directly from terminal alkynes and with N-halosuccinimides (halo = Br and I) or N-cholorophthalimide as the halogen sources, DBU as the activator, 1-haloalkynes were prepared in good to excellent yields at room temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA04736B

Reference48 articles.

1. Highly efficient two-step synthesis of (Z)-2-halo-1-iodoalkenes from terminal alkynes

2. Dual Role of Alkynyl Halides in One-Step Synthesis of Alkynyl Epoxides

3. Copper-Catalyzed C–H Cyanation of Terminal Alkynes with Cyanogen Iodide

4. One-Pot Synthesis of 1-Iodoalkynes and Trisubstituted Alkenes from Benzylic and Allylic Bromides

5. Poly(diiododiacetylene): Preparation, Isolation, and Full Characterization of a Very Simple Poly(diacetylene)

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