Coordination complexes constructed from pyrazole–acetamide and pyrazole–quinoxaline: effect of hydrogen bonding on the self-assembly process and antibacterial activity

Author:

Chkirate Karim1,Karrouchi Khalid2ORCID,Chakchak Hind3,Mague Joel T.4ORCID,Radi Smaail5ORCID,Adarsh N. N.6ORCID,Li Weiyang7,Talbaoui Ahmed8,Essassi El Mokhtar1,Garcia Yann7ORCID

Affiliation:

1. Laboratory of Heterocyclic Organic Chemistry, Department of Chemistry, Faculty of Sciences, Mohamed V University, BP1014, Rabat, 10100, Morocco

2. Laboratory of Analytical Chemistry and Bromatology, Faculty of Medicine and Pharmacy, Mohammed V University in Rabat, Morocco

3. Unités d'Appui Techniques À la Recherche Scientifique (UATRS), Centre National Pour la Recherche Scientifique et Technique (CNRST), Rabat, 10000, Morocco

4. Mohammed First University, Oujda, Faculty of Sciences Oujda, LCAE, Oujda, Morocco

5. LCAE, Département de Chimie, Faculté des Sciences, Université Mohamed I, BP 524, 60 000 Oujda, Morocco

6. School of Chemical Sciences, Mahatma Gandhi University, Kottayam, 686560, Kerala, India

7. Institute of Condensed Matter and Nanosciences, Molecular Chemistry, Materials and Catalysis (IMCN/MOST), Université catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-Neuve, Belgium

8. Laboratoire de Biologie des Pathologies Humaines, Faculté des Sciences, Université Mohammed V de Rabat, Morocco

Abstract

Two mononuclear coordination complexes of N-(2-aminophenyl)-2-(5-methyl-1H-pyrazol-3-yl)acetamide (L1) and one mononuclear complex, obtained after in situ oxidation of L1, have been synthesized and characterized spectroscopically.

Funder

Fonds De La Recherche Scientifique - FNRS

Centre National pour la Recherche Scientifique et Technique

Wallonie-Bruxelles International

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference73 articles.

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2. European Centre for Disease Prevention and Control, Antibiotic Resistance: An Increasing Threat to Human Health, 2018, https://antibiotic.ecdc.europa.eu/en/publications-data/antibiotic-resistanceincreasing-threat-human-health , accessed on 18 Jan. 2022

3. Atlanta, GA: US Centers for Disease Control and Prevention, Antibiotic Resistance Threats in the United States, 2019, https://www.cdc.gov/drugresistance/pdf/threats-report/2019-ar-threatsreport-508.pdf , accessed on 18 Jan. 2022

4. Geneva: World Health Organization, Antimicrobial resistance, https://www.who.int/news-room/fact-sheets/detail/antimicrobial-resistance ,accessed on 18 Jan. 2022

5. Synthetic strategies, crystal structures and biological activities of metal complexes with the members of azole family: A review

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