Robust non-covalent and covalent anchored N,N,N′,N’-tetramethyl-p-phenylenediamine derivative on electrode surface via spontaneous physical immobilization and in situ generated aryldiazonium ion electro-grafting: implication for on-surface chemistry and electro-catalytic determinations

Author:

Taleghan Ghafari Mahsa1234,Varmaghani Fahimeh12345ORCID,Karimi Babak12345ORCID,Khakyzadeh Vahid1674ORCID

Affiliation:

1. Department of Chemistry

2. Institute for Advanced Studies in Basic Sciences (IASBS)

3. Zanjan

4. Iran

5. Research Center for Basic Sciences & Modern Technologies (RBST)

6. K. N. Toosi University of Technology

7. 15418 Tehran

Abstract

Redox active electrodes were fabricated via robust adsorption and electro-grafting of an electroactive diazonium ion. The electrodes have implications in post-functionalization as well as electro-catalytic activity.

Funder

Institute for Advanced Studies in Basic Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrochemistry,Spectroscopy,Environmental Chemistry,Biochemistry,Analytical Chemistry

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