Insight into the role of nitrogen in N-doped ordered mesoporous carbons for the spontaneous non-covalent attachment and electrografting of redox-active materials

Author:

Shamsvand Nasim1,Varmaghani Fahimeh12ORCID,Karimi Babak12ORCID,Hassanaki Hamzeh1

Affiliation:

1. Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137-66731, Iran

2. Research Center for Basic Sciences and Modern Technologies (RBST), Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137-66731, Iran

Abstract

A comparison of N-doped and N-free OMCs is studied for electrografting via diazonium salts and spontaneous attachment. The redox active-based N-doped OMC electrode functions as voltammetric pH electrode in both buffered and unbuffered solutions.

Funder

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrochemistry,Spectroscopy,Environmental Chemistry,Biochemistry,Analytical Chemistry

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