Two σ- and two π-dative quadruple bonds between the s-block element and transition metal in [BeM(CO)<sub>4</sub>; M = Fe − Os]-Reference-Cited by-同舟云学术

Two σ- and two π-dative quadruple bonds between the s-block element and transition metal in [BeM(CO)₄; M = Fe − Os]

Published:2022 Issue:34 Volume:24 Page:20183-20188
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Parambath Sneha¹^ORCID,Parameswaran Pattiyil¹^ORCID

Affiliation:

1. Department of Chemistry, National Institute of Technology Calicut, Kerala, India

Abstract

The bonding interaction between the metal fragment M(CO)4 and beryllium in BeM(CO)4 (M = Fe, Ru, and Os) can be best described by dative quadruple bonds, viz., two σ and two π dative bonds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP02331H

Reference67 articles.

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5. OCBBCO: A Neutral Molecule with Some Boron−Boron Triple Bond Character

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