Electrocatalytic hydrogen evolution reaction by a Ni(N<sub>2</sub>O<sub>2</sub>) complex based on 2,2′-bipyridine-Reference-Cited by-同舟云学术

Electrocatalytic hydrogen evolution reaction by a Ni(N₂O₂) complex based on 2,2′-bipyridine

Published:2023 Issue:3 Volume:10 Page:972-978
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Dressel Julia M.¹^ORCID,Cook Emma N.¹^ORCID,Hooe Shelby L.¹^ORCID,Moreno Juan J.¹^ORCID,Dickie Diane A.¹^ORCID,Machan Charles W.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Virginia, PO Box 400319, Charlottesville, VA 22904-4319, USA

Abstract

A Ni complex containing a N2O2 ligand is active for the hydrogen evolution reaction. Mechanistic studies suggest the formation of hydrogen-bonded adducts facilitates hydride formation and near barrierless hydride protonation.

Funder

University of Virginia

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D2QI01928K

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