Pre-equilibrium reactions involving pendent relays improve CO<sub>2</sub> reduction mediated by molecular Cr-based electrocatalysts-Reference-Cited by-同舟云学术

Pre-equilibrium reactions involving pendent relays improve CO₂ reduction mediated by molecular Cr-based electrocatalysts

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Moberg Megan E.¹^ORCID,Reid Amelia G.¹^ORCID,Dickie Diane A.¹^ORCID,Machan Charles W.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Virginia, PO Box 400319, Charlottesville, VA 22904-4319, USA

Abstract

Non-covalent interactions between reduced chromium complexes and a cationic acid during homogeneous carbon dioxide reduction introduce pre-equilibrium effects which impact the operating potential and turnover frequency of catalysis.

Funder

Basic Energy Sciences

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01981D

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