In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions-Reference-Cited by-同舟云学术

In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions

Published:2015 Issue:2 Volume:44 Page:480-483
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Yuan-Zhu¹²³⁴⁵,Gao Song¹²³⁴⁵,Sato Osamu⁶⁷⁸⁹

Affiliation:

1. Beijing National Laboratory for Molecular Sciences

2. State Key Laboratory of Rare Earth Materials Chemistry and Applications

3. College of Chemistry and Molecular Engineering

4. Peking University

5. 100871 Beijing

6. Institute for Materials Chemistry and Engineering

7. Kyushu University

8. Fukuoka

9. Japan

Abstract

An unprecedented azido-bridged chair-like [Co^II₁₀] SMM containing both tetra- and octahedral Co(ii) ions was prepared through an in situ [2 + 3] cyclo-addition reaction in a sealed system. Magnetic study showed that it exhibited overall intracluster ferromagnetic couplings and slow magnetic relaxation at both zero and non-zero applied fields.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03211J

Reference39 articles.

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2. Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials

3. Cobalt single-molecule magnet

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5. An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2‘-bithiazoline)(N3)2]n

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