Two azido-bridged [2×2] cobalt(ii) grids featuring single-molecule magnet behaviour

Author:

Guo Zhilin12345ORCID,Deng Yi-Fei1234,Zhang Yipei1234,Pikramenou Zoe5678,Zhang Yuan-Zhu1234ORCID

Affiliation:

1. Department of Chemistry

2. Southern University of Science and Technology (SUSTech)

3. Shenzhen

4. P. R. China

5. School of Chemistry

6. The University of Birmingham

7. Edgbaston B15 2TT

8. UK

Abstract

Two Co(ii) [2 × 2] grid-like clusters containing both pyridazine and azido bridges were reported to exhibit overall intramolecular ferromagnetic coupling and field-induced single-molecule magnet behavior with the effective energy barriers up to 56 K.

Funder

National Natural Science Foundation of China

University of Birmingham

Southern University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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