Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines-Reference-Cited by-同舟云学术

Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines

Published:2019 Issue:10 Volume:6 Page:1572-1576
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhao Zi-Biao¹²³⁴⁵^ORCID,Shi Lei¹²³⁴⁵^ORCID,Meng Fan-Jie¹²³⁴⁵,Li Yaming¹²³⁴⁵,Zhou Yong-Gui¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals

2. School of Chemistry

3. Dalian University of Technology

4. Dalian 116024

5. P. R. China

Abstract

An enantioselective palladium-catalyzed addition of arylboronic acids to seven-membered cyclic N-sulfonyl aldimines and ketimines has been developed, giving the chiral cyclic sulfonamides with excellent yields and up to 99% ee.

Funder

National Natural Science Foundation of China

Dalian Science and Technology Bureau

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C8QO01323C

Reference67 articles.

1. Anticancer and Antiviral Sulfonamides

2. Cyclic sulfonamides via the ring-closing metathesis reaction

3. New (Sulfonyloxy)piperazinyldibenzazepines as Potential Atypical Antipsychotics: Chemistry and Pharmacological Evaluation

4. Asymmetric Synthesis of the Balanol Heterocycle via a Palladium-Mediated Epimerization and Olefin Metathesis

5. Iridium Catalyzed Asymmetric Hydrogenation of Cyclic Imines of Benzodiazepinones and Benzodiazepines

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