Nucleophilic addition reactions to nitrilium derivatives [B12H11NCCH3]− and [B12H11NCCH2CH3]−. Synthesis and structures of closo-dodecaborate-based iminols, amides and amidines-Reference-Cited by-同舟云学术

Nucleophilic addition reactions to nitrilium derivatives [B₁₂H₁₁NCCH₃]⁻ and [B₁₂H₁₁NCCH₂CH₃]⁻. Synthesis and structures of closo-dodecaborate-based iminols, amides and amidines

Published:2022 Issue:8 Volume:51 Page:3051-3059
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Laskova Julia¹^ORCID,Ananiev Ivan¹²^ORCID,Kosenko Irina¹,Serdyukov Alexander¹³^ORCID,Stogniy Marina¹³^ORCID,Sivaev Igor¹^ORCID,Grin Mikhail³,Semioshkin Andrey¹,Bregadze Vladimir I.¹

Affiliation:

1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Str., 119991, Moscow, Russia

2. G.V. Plekhanov Russian University of Economics, 117997, 36, Stremyanny line, Moscow, Russia

3. M. V. Lomonosov Institute of Fine Chemical Technology, MIREA – Russian Technological University, 86 Vernadsky Av., 119571, Moscow, Russia

Abstract

Nucleophilic addition reactions to the activated triple bond of the nitrilium derivatives of the closo-dodecaborate anion were studied.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04174F

Reference53 articles.

1. Hückel's Rule of Aromaticity Categorizes Aromatic closo Boron Hydride Clusters

2. Chemistry of closo-Dodecaborate Anion [B12H12]2-: A Review

3. Theoretical Study of closo-Borate Anions [BnHn]2− (n = 5–12): Bonding, Atomic Charges, and Reactivity Analysis

4. Synthesis and Properties of the Weakly Coordinating Anion [Me 3 NB 12 Cl 11 ] −

5. Halogenated closo ‐Dodecaborate Anions Stabilize Weakly Bound [(Me 3 NH) 3 X] 2+ (X = Cl, Br) Dications in the Solid State

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