Alkoxysulfonyl radical species: acquisition and transformation towards sulfonate esters through electrochemistry-Reference-Cited by-同舟云学术

Alkoxysulfonyl radical species: acquisition and transformation towards sulfonate esters through electrochemistry

Published:2022 Issue:40 Volume:13 Page:11785-11791
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Chun¹,Yang Man¹,Qiu Yanjie¹,Song Meijun¹,Wang Hongyan¹,Yang Min¹^ORCID,Xie Wenlin²,Wu Jie¹³⁴^ORCID,Ye Shengqing¹^ORCID

Affiliation:

1. School of Pharmaceutical and Materials Engineering & Institute for Advanced Studies, Taizhou University, 1139 Shifu Avenue, Taizhou 318000, China

2. School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China

3. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China

4. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China

Abstract

A new route to provide alkoxysulfonyl radical species via electrochemical anodic oxidation of inorganic sulfites with alcohols is developed, affording sulfonate esters by subsequent alkene difunctionalization with these alkoxysulfonyl radicals.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Henan Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC04027A

Reference54 articles.

1. Vinyl Sulfonate Esters and Vinyl Sulfonamides: Potent, Irreversible Inhibitors of Cysteine Proteases