A Photoinduced Three‐Component Reaction of Thianthrenium salts, DABCO ⋅ (SO<sub>2</sub>)<sub>2</sub>, and Benzyl Ether Substituted Alkenes-Reference-Cited by-同舟云学术

A Photoinduced Three‐Component Reaction of Thianthrenium salts, DABCO ⋅ (SO₂)₂, and Benzyl Ether Substituted Alkenes

Published:2024-07-11 Issue:14 Volume:366 Page:3130-3137
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Zhang Ji¹,Cen Jiayin²,Ye Shengqing²,Zheng Danqing¹^ORCID,Wu Jie²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University South Puzhu Road 30 Nanjing 210009 People's Republic of China

2. School of Pharmaceutical and Materials Engineering & Institute for Advanced Studies Taizhou University 1139 Shifu Avenue Taizhou 318000 People's Republic of China

3. State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032 People's Republic of China

4. School of Chemistry and Chemical Engineering Henan Normal University Xinxiang 453007 People's Republic of China

5. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Zhejiang Normal University Jinhua 321004 People's Republic of China

Abstract

AbstractA photoinduced three‐component reaction of thianthrenium salts, DABCO ⋅ (SO2)2, and benzyl ether substituted alkenes is developed, affording δ‐hydroxylsulfones with good functional group tolerance. This transformation proceeds through an anti‐Markovnikov hydrosulfonylation of alkenes under a mild reaction condition. Mechanism studies indicates that this reaction undergoes a radical pathway involving sulfur dioxide insertion and 1,5‐hydrogen transfer processes.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Natural Science Foundation of Jiangsu Province

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202400290

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