A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates-Reference-Cited by-同舟云学术

A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates

Published:2017 Issue:27 Volume:53 Page:3854-3857
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Noor Asif¹²³⁴,Li Jiawei¹²³⁴,Khairallah George N.¹²³⁴,Li Zhen¹²³⁴,Ghari Hossein⁵⁶⁷⁸⁹,Canty Allan J.¹⁰¹¹¹²⁴^ORCID,Ariafard Alireza⁵⁶⁷⁸⁹^ORCID,Donnelly Paul S.¹²³⁴^ORCID,O'Hair Richard A. J.¹²³⁴^ORCID

Affiliation:

1. School of Chemistry and Bio21 Molecular Science and Biotechnology Institute

2. University of Melbourne

3. Melbourne

4. Australia

5. Department of Chemistry

6. Faculty of Science

7. Central Tehran Branch

8. Islamic Azad University

9. Tehran

10. School of Physical Sciences

11. University of Tasmania

12. Hobart

Abstract

A palladium mediated synthesis of thioamides from aromatic carboxylic acids and substituted isothiocyanates was discovered by gas-phase experiments and theoretical studies.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC00865A

Reference31 articles.

1. R. M. Roberts , Serendipity: Accidental Discoveries, Science, Wiley, 1989

2. Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity

3. Contemporary screening approaches to reaction discovery and development

4. Inventing Reactions, ed. L. J. Gooßen, Springer Berlin Heidelberg, 2013

5. Computational prediction of small-molecule catalysts

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