Push–pull thiophene-based small molecules with donor and acceptor units of varying strength for photovoltaic application: beyond P3HT and PCBM

Author:

Marinelli Martina1,Candini Andrea23ORCID,Monti Filippo2ORCID,Boschi Alex2ORCID,Zangoli Mattia23ORCID,Salatelli Elisabetta1ORCID,Pierini Filippo4ORCID,Lanzi Massimiliano1ORCID,Zanelli Alberto2ORCID,Gazzano Massimo2ORCID,Di Maria Francesca23ORCID

Affiliation:

1. Department of Industrial Chemistry “Toso Montanari”, University of Bologna, Viale Risorgimento 4, 40136 Bologna, Italy

2. CNR-ISOF, Via P. Gobetti 101, 40129-Bologna, Italy

3. CLAN-Center for Light Activated Nanostructures, Università di Bologna and CNR, Via Gobetti 101, 40129 Bologna, Italy

4. Department of Biosystems and Soft Matter, Institute of Fundamental Technological Research, Polish Academy of Sciences, ul. Pawinskiego 5B, 02-106 Warsaw, Poland

Abstract

Here is reported the synthesis of a family of thiophene-based heptamers alternating electron donor (D) and acceptor (A) units in a D–A′–D–A–D–A′–D sequence. Their multiple roles as active materials in BHJ solar cells are presented.

Funder

Narodowe Centrum Badań i Rozwoju

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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