The oxygen-resistant [FeFe]-hydrogenase CbA5H harbors an unknown radical signal-Reference-Cited by-同舟云学术

The oxygen-resistant [FeFe]-hydrogenase CbA5H harbors an unknown radical signal

Published:2022 Issue:24 Volume:13 Page:7289-7294
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Heghmanns Melanie¹^ORCID,Rutz Andreas²^ORCID,Kutin Yury¹,Engelbrecht Vera²,Winkler Martin³,Happe Thomas²^ORCID,Kasanmascheff Müge¹^ORCID

Affiliation:

1. TU Dortmund University, Department of Chemistry and Chemical Biology, Otto-Hahn-Straße 6, 44227 Dortmund, Germany

2. Ruhr University Bochum, Faculty of Biology and Biotechnology, Photobiotechnology, Universitätsstr. 150, 44801 Bochum, Germany

3. Technical University of Munich Campus Straubing for Biotechnology and Sustainability, Professorship for Electrobiotechnology, Uferstrasse 53, 94315 Straubing, Germany

Abstract

Electron paramagnetic resonance spectroscopy revealed an unprecedented radical species in the oxygen-resistant [FeFe]-hydrogenase CbA5H. Analysis of the isotope-sensitive data suggests that it is related to the active site, the H-cluster.

Funder

Studienstiftung des Deutschen Volkes

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC00385F

Reference47 articles.

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