Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin

Author:

Gong Li12,Zhao Shiling3ORCID,Yu Jing14,Li Junshan5,Arbiol Jordi46ORCID,Kallio Tanja7ORCID,Calcabrini Mariano8ORCID,Martínez-Alanis Paulina R.1,Ibáñez Maria8ORCID,Cabot Andreu16ORCID

Affiliation:

1. Catalonia Institute for Energy Research – IREC Sant Adrià de Besòs, Barcelona 08930, Spain

2. University of Barcelona, Barcelona 08028, Spain

3. School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China

4. Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and BIST, Campus UAB, Bellaterra, 08193 Barcelona, Spain

5. Institute of Advanced Study, Chengdu University, Chengdu 610106, China

6. ICREA, Pg. Lluís Companys 23, 08010 Barcelona, Spain

7. Department of Chemistry and Materials Science, Aalto University School of Chemical Engineering, P.O. Box 16100, FI-00076 Aalto, Finland

8. IST Austria, Am Campus 1, Klosterneuburg 3400, Austria

Abstract

Modifying the surface of Cu2S nanoparticles with OAm significantly influenced the selectivity of the BZH reduction reaction. Bare Cu2S favored the production of BA, while OAm-capped Cu2S promoted HDB formation.

Funder

China Scholarship Council

Ministerio de Ciencia e Innovación

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

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