Regioselective CF2 functionalization of Sc3N@D3h(5)-C78-Reference-Cited by-同舟云学术

Regioselective CF2 functionalization of Sc3N@D3h(5)-C78

Published:2022 Issue:3 Volume:51 Page:1182-1190
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pykhova Anastasia D.¹,Semivrazhskaya Olesya O.¹,Samoylova Nataliya A.²,Popov Alexey A.²^ORCID,Ioffe Ilya N.¹^ORCID,Goryunkov Alexey A.¹^ORCID

Affiliation:

1. Chemistry Department, Lomonosov Moscow State University, Leninskie Gory, 1-3, 119991 Moscow, Russia

2. Leibniz Institute for Solid State and Materials Research, 01069 Dresden, Germany

Abstract

CF2 addition to Sc3N@D3h(5)-C78 proceeds regioselectively and much readier than to Sc3N@C80. The resulting Sc3N@C78(CF2) is a kinetically controlled closed product considerably less favorable energetically than several alternative open isomers.

Funder

Russian Science Foundation

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04031F

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