Base assisted C–C coupling between carbonyl and polypyridyl ligands in a Ru-NADH-type carbonyl complex
Author:
Affiliation:
1. Institute for Cell-Material Sciences
2. Kyoto University
3. Kyoto 612-8374
4. Japan
5. Kyoto 615-8530
6. Kyoto 606-8501
7. Institute for Liberal Arts and Sciences
Abstract
Strong organic base assists quantitative conversion of ruthenium(ii)-NADH-type complex to new metallacycle which was further oxidized to Ru-OCO-bridge complex upon reaction with aq. NH4PF6 under air.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00312A
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