Rhodium catalysts with cofactor mimics for the biomimetic reduction of CN bonds

Author:

Tang Jie12345,Dong Wenjin12345,Chen Fushan6785,Deng Li12345ORCID,Xian Mo12345

Affiliation:

1. CAS Key Laboratory of Bio-based Materials

2. Qingdao Institute of Bioenergy and Bioprocess Technology

3. Chinese Academy of Sciences

4. Qingdao 266101

5. P.R. China

6. College of Chemical Engineering

7. Qingdao University of Sciences & Technology

8. Qingdao

Abstract

Bio-inspired reduction of CN bonds was successfully performed using rhodium catalysts containing cofactor mimics. The intramolecular cooperation between rhodium and cofactor mimics enabled the transformation with good selectivity. A plausible mechanism was also proposed.

Funder

Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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