Fine-tuning of the size of supramolecular nanotoroids suppresses the subsequent catenation of nano-[2]catenane-Reference-Cited by-同舟云学术

Fine-tuning of the size of supramolecular nanotoroids suppresses the subsequent catenation of nano-[2]catenane

Published:2023 Issue:12 Volume:14 Page:3270-3276
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Itabashi Hiroki¹,Datta Sougata²^ORCID,Tsukuda Ryohei¹,Hollamby Martin J.³^ORCID,Yagai Shiki²⁴^ORCID

Affiliation:

1. Division of Advanced Science and Engineering, Graduate School of Science and Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan

2. Institute for Advanced Academic Research (IAAR), Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan

3. Department of Chemistry, School of Chemical and Physical Sciences, Keele University, Keele, Staffordsgire, ST55BG, UK

4. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, Chiba 263-8522, Japan

Abstract

The reduction in the inner diameter of the nanotoroids of a π-conjugated barbiturate monomer results in nano-[2]catenanes in a high yield due to enhanced secondary nucleation and subsequent steric suppression of further catenation.

Funder

Japan Society for the Promotion of Science

Mitsubishi Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC07063D

Reference49 articles.

1. Hierarchically self-assembled homochiral helical microtoroids

2. Supramolecular double-stranded Archimedean spirals and concentric toroids