Distinct seed topologies enable comparison of elongation and secondary nucleation pathways in seeded supramolecular polymerization

Author:

Itabashi Hiroki1,Tashiro Keigo2ORCID,Koshikawa Shumpei1,Datta Sougata3ORCID,Yagai Shiki34ORCID

Affiliation:

1. Division of Advanced Science and Engineering, Graduate School of Science and Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan

2. Department of Applied Chemistry, Faculty of Science and Technology, Seikei University, 3-3-1 Kichijoji-kitamachi, Musashino-shi, Tokyo, 180-8633, Japan

3. Institute for Advanced Academic Research (IAAR), Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan

4. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, Chiba 263-8522, Japan

Abstract

Toroidal and helicoidal supramolecular polymers allow us to observe distinct kinetics of secondary nucleation on the aggregate surface and elongation from the facet of aggregate termini on seeded supramolecular polymerization.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Mitsubishi Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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