Short vs. long chains competition during “grafting to” process from melt

Author:

Chiarcos Riccardo1ORCID,Antonioli Diego1,Gianotti Valentina1ORCID,Laus Michele1,Munaò Gianmarco2,Milano Giuseppe3,De Nicola Antonio4ORCID,Perego Michele5ORCID

Affiliation:

1. Dipartimento di Scienze e Innovazione Tecnologica (DISIT), Universitá del Piemonte Orientale “A. Avogadro”, Viale T. Michel 11, 15121 Alessandria, Italy

2. Dipartimento di Scienze Matematiche e Informatiche, Scienze Fisiche e Scienze della Terra, Università degli Studi di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina, Italy

3. Department of Chemical, Materials and Production Engineering, University of Naples Federico II, Naples 80125, Italy

4. Scuola Superiore Meridionale, University of Naples Federico II, Largo S. Marcellino 10, Naples 80138, Italy

5. CNR-IMM, Unit of Agrate Brianza, Via C. Olivetti 2, 20864 Agrate Brianza, Italy

Abstract

A preferential grafting of short chains occurs during the “grafting to” reaction of hydroxy terminated P(S-st-MMA) blends consisting of short and long chains. The enrichment is enhanced when the chain length difference increases.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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