Structural variation in cerium aryloxide complexes templated by hemilabile K+–amine interactions
Author:
Affiliation:
1. P. Roy and Diana T. Vagelos Laboratories
2. Department of Chemistry
3. University of Pennsylvania
4. Philadelphia
5. USA
Abstract
Variation of aryloxide substituents using the cerium bdmmp framework provided a structural diversity for study by NMR, crystallography and electrochemistry.
Funder
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C5NJ00848D
Reference22 articles.
1. Advances in Structurally Characterized Lanthanide Alkoxide, Aryloxide, and Silyloxide Compounds
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3. Synthesis and Structural Characterization of a Series of Carboxylic Acid Modified Cerium(III) Alkoxides
4. Synthesis, structure, and reactivity of polymetallic sodium and lanthanum 4-methylphenoxide complexes
5. Alkali Metal Induced Structural Changes in Complexes Containing Anionic Lanthanum Aryloxide Moieties. X-ray Crystal Structures of (THF)La(OAr)2(μ-OAr)2Li(THF), (THF)La(OAr)2(μ-OAr)2Na(THF)2, and CsLa(OAr)4 (Ar = 2,6-i-Pr2C6H3)
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1. A structural and spectroscopic overview of molecular lanthanide complexes with fluorinated O-donor ligands;Coordination Chemistry Reviews;2020-02
2. Redox-enhanced hemilability of a tris(tert-butoxy)siloxy ligand at cerium;Dalton Transactions;2018
3. Density Functional Theory as a Predictive Tool for Cerium Redox Properties in Nonaqueous Solvents;Inorganic Chemistry;2016-11-30
4. 1,2-Addition or Enolization? Variable Reactivity of a Cerium Acetylide Complex toward Carbonyl Compounds;Organometallics;2016-06-06
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