New insights into H<sub>2</sub>activation by intramolecular frustrated Lewis pairs based on aminoboranes: the local electrophilicity index of boron as a suitable indicator to tune the reversibility of the process-Reference-Cited by-同舟云学术

New insights into H₂activation by intramolecular frustrated Lewis pairs based on aminoboranes: the local electrophilicity index of boron as a suitable indicator to tune the reversibility of the process

Published:2023 Issue:42 Volume:14 Page:11798-11808
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Barrales-Martínez César¹^ORCID,Durán Rocío¹^ORCID,Jaque Pablo²³^ORCID

Affiliation:

1. Instituto de Investigación Interdisciplinaria (I3), Vicerrectoría Académica and Centro de Bioinformática, Simulación y Modelado (CBSM), Facultad de Ingeniería, Universidad de Talca, Campus Lircay, Talca 3460000, Chile

2. Departamento de Química Orgánica y Fisicoquímica, Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Sergio Livingstone 1007, Independencia, Santiago, Chile

3. Centro de Modelamiento Molecular, Biofísica y Bioinformática, CM2B2, Universidad de Chile, Sergio Livingstone 1007, Independencia, Santiago, Chile

Abstract

The condensed-to-boron electrophilicity index (ωB) is a tunable property to rationally perform modifications for reaching reversibility in H2activation by intramolecular aminoborane frustrated Lewis pairs.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC03992G

Reference49 articles.

1. Hydrogen energy

2. A green hydrogen economy

3. Green hydrogen as an alternative fuel for the shipping industry

4. Activation of dihydrogen and coordination of molecular H2 on transition metals

5. Frustrated Lewis Pairs

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