SO2 and SO3 reactions with [(C5Me5)2Sm-O-Sm(C5Me5)2]: a DFT investigation and comparison with CO2 reactivity-Reference-Cited by-同舟云学术

SO2 and SO3 reactions with [(C5Me5)2Sm-O-Sm(C5Me5)2]: a DFT investigation and comparison with CO2 reactivity

Published:2017 Issue:24 Volume:46 Page:7660-7663
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Louyriac Elisa¹²³⁴⁵,Roesky Peter W.⁶⁷⁸⁹,Maron Laurent¹²³⁴⁵

Affiliation:

1. LPCNO

2. Université de Toulouse

3. CNRS

4. INSA

5. UPS

6. Institute of Inorganic Chemistry

7. Karlsruhe Institute of Technology (KIT)

8. 76131 Karlsruhe

9. Germany

Abstract

Samarocene oxide [Cp*₂Sm-O-SmCp*₂] with Cp* = C₅Me₅, often seen as an undesirable product resulting from the oxidation of samarocene, has been reported to react with organic and inorganic anhydrides.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01703K

Reference21 articles.

1. Solution synthesis and crystallographic characterization of the divalent organosamarium complexes (C5Me5)2Sm(THF)2 and [(C5Me5)Sm(.mu.-I)(THF)2]2

2. W. J. Evans , T. A.Ulibarri, H.Schumann and S.Nickel, Inorganic Syntheses, John Wiley & Sons, 2007, vol. 27, p. 155

3. Synthesis and x-ray crystallographic characterization of an oxo-bridged bimetallic organosamarium complex, [(C5Me5)2Sm]2(.mu.-O)

4. Structural studies of lanthanide and yttrium metallocene oxides

5. Samarocene oxide: from an undesired decomposition product to a new reagent

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