Samarocene oxide: from an undesired decomposition product to a new reagent-Reference-Cited by-同舟云学术

Samarocene oxide: from an undesired decomposition product to a new reagent

Published:2016 Issue:40 Volume:52 Page:6654-6657
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Schoo Christoph¹²³,Klementyeva Svetlana V.¹²³⁴⁵,Gamer Michael T.¹²³,Konchenko Sergey N.¹²³⁶⁷,Roesky Peter W.¹²³

Affiliation:

1. Institute of Inorganic Chemistry Karlsruhe Institute of Technology (KIT)

2. 76131 Karlsruhe

3. Germany

4. G.A. Razuvaev Institute of Organometallic Chemistry RAS

5. 603950 Nizhny Novgorod

6. Nikolaev Institute of Inorganic Chemistry SB RAS

7. 630090 Novosibirsk

Abstract

Samarocene oxide [Cp*₂Sm-O-SmCp*₂], which is mostly considered as an undesired decomposition product, may act as a mild oxide base and thus is a valuable synthetic equivalent for “O²⁻”.

Funder

German Academic Exchange Service London Office

Deutsche Forschungsgemeinschaft

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC02450E

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4. Investigation of organolanthanide-based carbon-carbon bond formation: synthesis, structure, and coupling reactivity of organolanthanide alkynide complexes, including the unusual structures of the trienediyl complex [(C5Me5)2Sm]2[.mu.-.eta.2:.eta.2-Ph(CH2)2C:C:C:C-(CH2)2Ph] and the unsolvated alkynide [(C5Me5)2Sm(C.tplbond.CCMe3)]2

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