Alkaline earth metal-assisted dinitrogen activation at nickel

Author:

Knoell Theresa1,Polanco Jocelyn1,MacMillan Samantha N.2ORCID,Bertke Jeffery A.3ORCID,Foroutan-Nejad Cina4ORCID,Lancaster Kyle M.2ORCID,‘Gus’ Bakhoda Abolghasem1ORCID

Affiliation:

1. Department of Chemistry Towson University, 8000 York Road, Towson, MD 21252, USA

2. Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY, USA

3. Georgetown University, Department of Chemistry, Washington, DC 20057, USA

4. Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

Abstract

Rare examples of trinuclear [Ni–N2–M–N2–Ni] core (M = Ca, Mg) with linear bridged dinitrogen ligands are reported in this work.

Funder

Narodowym Centrum Nauki

Infrastruktura PL-Grid

U.S. Department of Energy

National Institutes of Health

National Institute of General Medical Sciences

Jess and Mildred Fisher College of Science and Mathematics

Directorate for Biological Sciences

Publisher

Royal Society of Chemistry (RSC)

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