Mechanistic insights into the catalytic carbonyl hydrosilylation by cationic [CpM(CO)2(IMes)]+ (M = Mo, W) complexes: the intermediacy of η1-H(Si) metal complexes-Reference-Cited by-同舟云学术

Mechanistic insights into the catalytic carbonyl hydrosilylation by cationic [CpM(CO)2(IMes)]+ (M = Mo, W) complexes: the intermediacy of η1-H(Si) metal complexes

Published:2018 Issue:7 Volume:42 Page:4923-4932
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Fang Shaoqin¹²³⁴⁵,Chen Hongcai¹²³⁴⁵,Wang Wenmin¹²³⁴⁵,Wei Haiyan¹²³⁴⁵^ORCID

Affiliation:

1. Jiangsu Collaborative Innovation Center of Biomedical Functional Materials

2. Jiangsu Provincial Key Laboratory for NSLSCS

3. Jiangsu Key Laboratory of Biomedical Materials

4. School of Chemistry and Materials Science

5. Nanjing Normal University

Abstract

The ionic S_N2-type mechanistic pathway initiated by silane end-on coordination on the metal centers, forming η¹-H(Si) Mo/W complexes, is the preferred reaction pathway for the two cationic cyclopentadienyl molybdenum/tungsten complexes, [CpM(CO)₂(IMes)]⁺ (M = Mo, W) in catalyzing carbonyl hydrosilylation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ03856A

Reference183 articles.

1. Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal Silyl Compounds

2. Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

3. A Review of Recent Progress in Catalyzed Homogeneous Hydrosilation (Hydrosilylation)

4. Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

5. Reduction of carbonyl compounds via hydrosilylation

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Experimental Mechanistic Analysis of Carbonyl Hydrosilylation Catalyzed by Abu-Omar’s Rhenium(V) Oxo Complex;Organometallics;2022-12-27

2. Activation of Si–H and B–H bonds by Lewis acidic transition metals and p-block elements: same, but different;Chemical Science;2022

3. Recent progress on NHC-stabilized early transition metal (group 3–7) complexes: Synthesis and applications;Coordination Chemistry Reviews;2020-11

4. Si–H Bond Activation with Bullock’s Cationic Tungsten(II) Catalyst: CO as Cooperating Ligand;Journal of the American Chemical Society;2019-11-06

5. Theoretical prediction of Ni(I)‐catalyst for hydrosilylation of pyridine and quinoline;Journal of Computational Chemistry;2019-06-11