Activation of Si–H and B–H bonds by Lewis acidic transition metals and p-block elements: same, but different-Reference-Cited by-同舟云学术

Activation of Si–H and B–H bonds by Lewis acidic transition metals and p-block elements: same, but different

Published:2022 Issue:25 Volume:13 Page:7392-7418
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ríos Pablo¹^ORCID,Rodríguez Amor¹^ORCID,Conejero Salvador¹^ORCID

Affiliation:

1. Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica CSIC and Universidad de Sevilla, Centro de Innovación en Química Avanzada (ORFEO-CINQA), C/Américo Vespucio 49, 41092, Sevilla, Spain

Abstract

In this Perspective we compare the ability of transition metals and p-block Lewis acids to activate electrophilically hydrosilanes and hydroboranes. The mechanistic similarities and dissimilarities in different catalytic transformations are analyzed.

Funder

Ministerio de Ciencia e Innovación

Junta de Andalucía

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02324E

Reference188 articles.

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