Synthesis, crystal polymorphism and spin crossover behavior of adamantylboron-capped cobalt(<scp>ii</scp>) hexachloroclathrochelate and its transformation into the CoIIICoIICoIII-bis-macrobicyclic derivative-Reference-Cited by-同舟云学术

Synthesis, crystal polymorphism and spin crossover behavior of adamantylboron-capped cobalt(ii) hexachloroclathrochelate and its transformation into the Co^IIICo^IICo^III-bis-macrobicyclic derivative

Published:2023 Issue:2 Volume:52 Page:347-359
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Belov Alexander S.¹²^ORCID,Novikov Valentin V.³,Vologzhanina Anna V.²^ORCID,Pavlov Alexander A.²⁴^ORCID,Bogomyakov Artem S.⁵^ORCID,Zubavichus Yan V.⁶^ORCID,Svetogorov Roman D.⁷,Zelinskii Genrikh E.¹²,Voloshin Yan Z.¹²^ORCID

Affiliation:

1. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 31 Leninsky pr., 119991 Moscow, Russia

2. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 28-1 Vavilova st., 119334 Moscow, Russia

3. Moscow Institute of Physics and Technology, 141700 Moscow Region, Russia

4. National Research University Higher School of Economics, 101000 Moscow, Russia

5. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia

6. Synchrotron Radiation Facility SKIF, G.K. Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, 1 Nikolskii pr., 630559 Koltsovo, Russia

7. National Research Center Kurchatov Institute, 123182 Moscow, Russia

Abstract

Cobalt(ii) clathrochelate [Co(Cl2Gm)3(BAd)2] undergoes a temperature-induced spin crossover. Its prolonged crystallization unexpectedly gave the crystals of CoIIICoIICoIII-trinuclear bis-clathrochelate [[CoIII(Cl2Gm)3(BAd)]2CoII].

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03300C

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