Effects of solvatomorphism, the nature of a chelating ligand synthon and a counterion on the single crystal XRD structure and SMM properties of paramagnetic monocapped cobalt(<scp>ii</scp>) tris-pyrazoloximates-Reference-Cited by-同舟云学术

Effects of solvatomorphism, the nature of a chelating ligand synthon and a counterion on the single crystal XRD structure and SMM properties of paramagnetic monocapped cobalt(ii) tris-pyrazoloximates

Published:2024 Issue:4 Volume:53 Page:1482-1491
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Belova Svetlana A.¹²^ORCID,Belov Alexander S.¹²^ORCID,Danshina Anastasia A.¹³^ORCID,Zubavichus Yan V.⁴^ORCID,Aleshin Dmitriy Yu.²^ORCID,Pavlov Alexander A.¹⁵^ORCID,Efimov Nikolay N.²^ORCID,Voloshin Yan Z.¹²^ORCID

Affiliation:

1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28-1 Vavilova St., 119334 Moscow, Russia

2. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 31 Leninsky Prosp., 119991 Moscow, Russia

3. Moscow Institute of Physics and Technology (National Research University), 9 Institutskiy per., 141700 Dolgoprudny, Moscow Region, Russia

4. Synchrotron Radiation Facility SKIF, Boreskov Institute of Catalysis SB RAS, 630559 Koltsovo, Russia

5. BMSTU Center of National Technological Initiative “Digital Material Science: New Material and Substances”, Bauman Moscow State Technical University, 2nd Baumanskaya st. 5, 105005 Moscow, Russia

Abstract

All the title factors were found to substantially affect the molecular and crystal structure of these pseudomacrobicyclic cobalt(ii) intracomplexes as well as their SMM properties.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03025C

Reference53 articles.

1. Chloride Ion-Aided Self-Assembly of Pseudoclathrochelate Metal Tris-pyrazoloximates

2. A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior

3. Polymorphism in a Cobalt-Based Single-Ion Magnet Tuning Its Barrier to Magnetization Relaxation

4. Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy

5. Pseudoclathrochelate n-hexadecylboron-capped metal(II) tris-pyrazoloximates: synthesis, X-ray structure, spectral and magnetic characteristics

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