Design of nickel donor–acceptor dithiolenes for 2nd order nonlinear optics: an experimental and computational study

Author:

Attar Salahuddin S.12345ORCID,Marchiò Luciano6789ORCID,Pilia Luca101112139ORCID,Casula Maria F.101112139ORCID,Espa Davide141512169,Serpe Angela171812139ORCID,Pizzotti Maddalena191520219ORCID,Marinotto Daniele2223219ORCID,Deplano Paola141512169ORCID

Affiliation:

1. Texas A&M University at Qatar (TAMUQ)

2. Texas A&M Engineering Building

3. Education City

4. Doha

5. Qatar

6. Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale

7. Università di Parma

8. Parma

9. Italy

10. Dipartimento di Ingegneria Meccanica

11. Chimica e dei Materiali

12. Università di Cagliari

13. Cagliari

14. Dipartimento di Fisica

15. INSTM Research Unit

16. Monserrato

17. Dipartimento di Ingegneria Civile

18. Ambientale e Archittetura

19. Department of Chemistry

20. University of Milan

21. 20133 Milano

22. ISTM-CNR

23. Centro CIMAINA dell’Università degli Studi di Milano e UdR dell'INSTM

Abstract

This study, concerning the influence on the NLO properties of a remote functionality in the donor of D–Ni–A dithiolenes 1–4, allows to point out the relationship between NLO properties and the donor capability in modulating the low-energy absorption.

Funder

Fondazione Banco di Sardegna

Fondazione Cariplo

Università di Cagliari

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference49 articles.

1. J. Zyss , Molecular Nonlinear Optics: Materials, Physics and Devices , Academic Press , Boston , 1994

2. M. G. Papadopoulos , J.Leszczynski and A.Sadlej , Nonlinear Optical Properties of Matter: From Molecules to Condensed Phases , Springer , Dordrecht , 2006

3. B. J. Coe , in Non-Linear Optical Properties of Matter; Papadopoulos , ed. M. G. Sadlej , A. J. Leszczynski , Springer Verlag , Berlin , 2006 , p. 571

4. Recent developments in the field of metal complexes containing photochromic ligands: Modulation of linear and nonlinear optical properties

5. S. Di Bella , C.Dragonetti , M.Pizzotti , D.Roberto , F.Tessore and R.Ugo , in Topics in Organometallic Chemistry 28, Molecular Organometallic Materials for Optics , ed. H. Le Bozec , V. Guerchais , Springer , New York , 2010 , vol. 28, pp. 1–55

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