Substituent and redox effects on the second-order NLO response of Ru(<scp>ii</scp>) complexes with polypyridine ligands: a theoretical study-Reference-Cited by-同舟云学术

Substituent and redox effects on the second-order NLO response of Ru(ii) complexes with polypyridine ligands: a theoretical study

Published:2023 Issue:15 Volume:47 Page:7326-7334
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Wang Yingying¹,Chen Yu¹,Zhao Yuanyuan¹^ORCID,Qiu Yongqing¹^ORCID

Affiliation:

1. Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China

Abstract

Modifying ligands in four studied Ru(II) complexes have slight influence on their static first hyperpolarizabilities (βtot) values. However, the βtot values of complexes 1+/−–4+/− are all enhanced and the largest βtot value is observed for complex 4−.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ00594A

Reference70 articles.

1. Synthesis, Characterization, Optical Spectroscopic, Electronic Structure, and Second-Order Nonlinear Optical (NLO) Properties of a Novel Class of Donor−Acceptor Bis(salicylaldiminato)nickel(II) Schiff Base NLO Chromophores

2. Quadratic Nonlinearity of One- and Two-Electron Oxidized Metalloporphyrins and Their Switching in Solution

3. Syntheses and Quadratic Nonlinear Optical Properties of Salts Containing Benzothiazolium Electron-Acceptor Groups

4. Linear and Nonlinear Optical Properties of Cationic Bipyridyl Iridium(III) Complexes: Tunable and Photoswitchable?

5. Mono- and dinuclear sesquifulvalene complexes, organometallic materials with large nonlinear optical properties

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