A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms-Reference-Cited by-同舟云学术

A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms

Published:2017 Issue:48 Volume:46 Page:16812-16820
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ekanayake Danushka M.¹²³⁴,Kulesa Krista M.¹²³⁴,Singh Jaffarguriqbal¹⁵⁶⁴,Kpogo Kenneth K.¹²³⁴,Mazumder Shivnath¹⁵⁶⁴,Bernhard Schlegel H.¹²³⁴^ORCID,Verani Cláudio N.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Wayne State University

3. Detroit

4. USA

5. Hofstra University

6. Hempstead

Abstract

A copper catalyst is active towards water reduction with distinctive pH-dependent mechanisms. The Cu^III–H⁻ intermediate is bypassed by PCET processes.

Funder

Office of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02711G

Reference52 articles.

1. Molecular Cobalt Pentapyridine Catalysts for Generating Hydrogen from Water

2. Electrocatalytic Hydrogen Evolution in Acidic Water with Molecular Cobalt Tetraazamacrocycles

3. A tridentate Ni pincer for aqueous electrocatalytic hydrogen production