A facile and practical preparation of P-chiral phosphine oxides-Reference-Cited by-同舟云学术

A facile and practical preparation of P-chiral phosphine oxides

Published:2021 Issue:27 Volume:57 Page:3335-3338
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Xu Ronghua¹²³⁴,Gao Zhenhua⁵⁶⁴,Yu Yiteng⁷⁸⁹¹⁰¹¹,Tang Yehua¹²³⁴,Tian Duanshuai⁷⁸⁹¹⁰¹¹,Chen Tian⁷⁸⁹¹⁰¹¹,Chen Yibing¹²³⁴,Xu Guangqing⁷⁸⁹¹⁰¹¹,Shi Enxue⁵⁶⁴,Tang Wenjun¹²³⁴⁷^ORCID

Affiliation:

1. School of Physical Science and Technology

2. ShanghaiTech University

3. Shanghai 200031

4. China

5. State Key Laboratory of NBC Protection for Civilian

6. Beijing 102205

7. State Key Laboratory of Bio-Organic and Natural Products Chemistry

8. Center for Excellence in Molecular Synthesis

9. Shanghai Institute of Organic Chemistry

10. Chinese Academy of Sciences

11. Shanghai 200032

Abstract

A practical and cost-effective synthetic method of P-chiral diarylalkyl, aryldialkyl, and triaryl phosphine oxides by using readily available chiral diphenyl-2-pyrrolidinemethanol as the auxiliary is developed. The long-standing racemization issue during solvolysis has been addressed.

Funder

Science and Technology Commission of Shanghai Municipality

Chinese Academy of Sciences

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC00646K

Reference42 articles.

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2. New Chiral Phosphorus Ligands for Enantioselective Hydrogenation

3. A. Grabulosa , P-Stereogenic Ligands in Enantioselective Catalysis , RSC , Cambridge , 2011

4. Chiral Monophosphorus Ligands for Asymmetric Catalytic Reactions

5. P-Chiral Phosphorus Ligands Based on a 2,3-Dihydrobenzo[d][1,3]oxaphosphole Motif for Asymmetric Catalysis

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