Picosecond time-resolved infrared spectroscopy of rhodium and iridium azides

Author:

Portius Peter123,Meijer Anthony J. H. M.123,Towrie Michael4567,Crozier Benjamin F.123,Schiager Ingrid123

Affiliation:

1. Department of Chemistry

2. University of Sheffield

3. Sheffield, UK

4. Central Laser Facility

5. Research Complex at Harwell

6. STFC Rutherford Appleton Laboratory

7. , UK

Abstract

Ultrafast photochemical processes induced in the transition metal azido complexes Rh(Cp*)(N3)2(PPh3) and Ir(Cp*)(N3)2(PPh3) upon laser excitation at 266 nm and 400 nm were elucidated by picosecond time-resolved infrared spectroscopy and density functional theory.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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