Competition between N and O: use of diazineN-oxides as a test case for the Marcus theory rationale for ambident reactivity-Reference-Cited by-同舟云学术

Competition between N and O: use of diazineN-oxides as a test case for the Marcus theory rationale for ambident reactivity

Published:2020 Issue:35 Volume:11 Page:9630-9647
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sheehy Kevin J.¹²³⁴⁵^ORCID,Bateman Lorraine M.¹²³⁴⁵^ORCID,Flosbach Niko T.⁶⁷⁸⁹,Breugst Martin⁶⁷⁸⁹^ORCID,Byrne Peter A.¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemistry

2. Analytical and Biological Chemistry Research Facility

3. University College Cork

4. Cork

5. Ireland

6. Department für Chemie

7. Universität zu Köln

8. 50939 Köln

9. Germany

Abstract

Marcus theory enables rationalisation and quantification of selectivities in reactions of ambident nucleophiles for which the HSAB principle cannot operate.

Funder

Irish Research Council

Science Foundation Ireland

Universität zu Köln

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC02834G

Reference128 articles.

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4. Hard and Soft Acids and Bases

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