Can one determine the density of an individual synthetic macromolecule?

Author:

Messmer Daniel12345ORCID,Sánchez-Ferrer Antoni62785ORCID,Tacke Sebastian9245,Yu Hao12345ORCID,Nüsse Harald10111213,Klingauf Jürgen10111213,Wepf Roger10111213ORCID,Kröger Martin12345ORCID,Halperin Avraham14151617,Mezzenga Raffaele62785ORCID,Schlüter A. Dieter12345ORCID

Affiliation:

1. Department of Materials

2. ETH Zürich

3. Polymer Chemistry & Polymer Physics

4. 8093 Zürich

5. Switzerland

6. Department of Health Sciences and Technology

7. Laboratory of Food and Soft Materials

8. 8092 Zürich

9. Scientific Center for Optical and Electron Microscopy

10. Institute of Medial Physics and Biophysics

11. Westfälische Wilhelms-Universität Münster

12. 48149 Münster

13. Germany

14. Laboratoire de Spectrometrie Physique

15. CNRS University Joseph Fourier

16. 38402 Saint Martin d’Hères cedex

17. France

Abstract

The determination of volumetric mass densities of dendronized polymers was attempted, utilizing the measurable physical dimensions these synthetic molecular objects possess.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

Reference41 articles.

1. V. Kholodovych and W. J.Welsh , Densities of Amorphous and Crystalline Polymers , in Physical Properties of Polymers Handbook , Springer New York , New York, NY , 2007 ; pp. 611–617

2. Polymer Mechanochemistry: From Destructive to Productive

3. Tension Amplification in Molecular Brushes in Solutions and on Substrates

4. “Fatal Adsorption” of Brushlike Macromolecules:  High Sensitivity of C−C Bond Cleavage Rates to Substrate Surface Energy

5. How Strong Is a Covalent Bond?

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