Site-selective radical reactions of kinetically stable open-shell singlet diradicaloid difluorenoheteroles with tributyltin hydride and azo-based radical initiators-Reference-Cited by-同舟云学术

Site-selective radical reactions of kinetically stable open-shell singlet diradicaloid difluorenoheteroles with tributyltin hydride and azo-based radical initiators

Published:2023 Issue:22 Volume:14 Page:5974-5982
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tabata Naoki¹,Uchino Takumi¹,Kitamura Chitoshi¹,Yoshizawa Kazunari²^ORCID,Shiota Yoshihito²^ORCID,Kato Shin-ichiro¹^ORCID

Affiliation:

1. Department of Materials Chemistry, School of Engineering, The University of Shiga Prefecture, 2500 Hassaka-cho, Hikone, Shiga 522-8533, Japan

2. Institute for Materials Chemistry and Engineering (IMCE), Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

Kinetically stable open-shell singlet diradicaloids regioselectively react with radical species generated from azo-based radical initiators as well as HSn(n-Bu)3.

Funder

Asahi Glass Foundation

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00381G

Reference41 articles.

1. Diradicals

2. Recent Progress in Quinoidal Singlet Biradical Molecules

3. Theoretical Design of Open-Shell Singlet Molecular Systems for Nonlinear Optics

4. Recent progress in open-shell organic conjugated materials and their aggregated states

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