Isomerism tunes the diradical character of difluorenopyrroles at constant Hückel-level anti-aromaticity-Reference-Cited by-同舟云学术

Isomerism tunes the diradical character of difluorenopyrroles at constant Hückel-level anti-aromaticity

Published:2023 Issue:46 Volume:14 Page:13468-13474
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Moriyasu Ryotaro¹,Quintero Sergio Moles²^ORCID,Gómez-García Carlos J.³^ORCID,Suzuki Kazumasa⁴^ORCID,Kitamura Chitoshi¹,Murata Michihisa⁵^ORCID,Alonso Mercedes⁶^ORCID,Casado Juan²^ORCID,Kato Shin-ichiro¹^ORCID

Affiliation:

1. Department of Materials Chemistry, School of Engineering, The University of Shiga Prefecture, 2500 Hassaka-cho, Hikone, Shiga 522-8533, Japan

2. Departament of Physical Chemistry, University of Málaga, Campus de Teatinos s/n, Málaga, 29071, Spain

3. Departament of Inorganic Chemsitry, University of Valencia, C/ DR. Moliner, 50, 46100 Brujassot, Valencia, Spain

4. Department of Material Chemistry, Graduate School of Engineering, Nagoya university, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan

5. Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi-ku, Osaka 535-8585, Japan

6. Eenheid Algemene Chemie (ALGC), Vrije Universiteit Brussel (VUB)Plei nlaan 2, 1050 Brussels, Belgium

Abstract

A new diradical based on diindenocarbazole or difluorenopyrrole was synthesized and experimentally characterized by optical, electrochemical, and magnetic techniques, as well as quantum chemical calculations.

Funder

Ministerio de Economía y Competitividad

Junta de Andalucía

Japan Society for the Promotion of Science

Yashima Environment Technology Foundation

Asahi Glass Foundation

Kyushu University

University of Shiga Prefecture

Vrije Universiteit Brussel

Publisher

Royal Society of Chemistry (RSC)

Subject